The research, carried out by Min Gu and friends at the Swinburne University of Technology in Melbourne, started with a suspension of graphene oxide (GO) in water. The suspension was then mixed with PVA (polyvinyl alcohol), spun coated on a glass disc, and left to dry. The end result is a disc covered in a GO polymer. This GO polymer is naturally highly fluorescent — but, by shining a two-photon femtosecond laser at the polymer, it can be turned into reduced GO, which isn’t fluorescent. (Reduced GO is essentially low-grade graphene.) It’s then easy enough to use another laser, paired with a photodetector, to read these non-fluorescent areas. Voila: Reading and writing to a GO-polymer optical disc.
If that wasn’t exciting enough,
the recording layer of these GO-polymer discs is thick enough that the
read/write lasers can be focused onto multiple layers. The refractive
index of the reduced GO can also be modulated, depending on how the
recording laser is used. With these two factors combined, these
GO-polymyer discs can be used as holographic storage. Without getting into the complexity of how holographic storage works,
it’s enough to say that it allows for incredibly high storage
densities. In this case, the Australians say they’ve reached a density
of around 0.2 terabits per cubic centimeter, or 3.2 terabits per cubic
inch. It’s hard to compare holographic to non-holographic storage, but
hard drives are slowly creeping towards 1 terabit per square inch, while Blu-ray discs are a few orders of magnitude less, in the gigabits-per-square-inch range.
As we’ve reported previously, one of the main stumbling blocks when it comes to the commercial adoption of graphene is its mass production. There is currently no way of producing large amounts of high-quality graphene. The reduction of graphene oxide to graphene is of particular interest because it’s easy and can be done in bulk — but so far, the resulting graphene is of low quality. Still, this hasn’t prevented cool research like the work here carried out by Swinburne, and similar work done by UCLA which used a DVD burner to create graphene that was then used in the construction of uber supercapacitors.
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